Short Communication

Photo-acoustic technique with widely tuneable laser: Metasurface circular dichroism response

¹ Department SBAI, Sapienza University of Rome, Via Antonio Scarpa 14-16, 00161 Rome, Italy
² Department of Physics and Astronomy, University of Padova, Via Marzolo 8, I-35131 Padova, Italy

^* Corresponding author: emilija.petronijevic@uniroma1.it

Received: 1 March 2024
Accepted: 3 April 2024

Abstract

Chirality, an intrinsic property of certain entities in the universe, is characterized by the absence of mirror symmetry. Understanding chirality is crucial as it influences molecular interactions and properties. Circular dichroism (CD), measured using circularly polarized light, is a standard technique for probing chirality, but its sensitivity is often limited. Here, we explore extrinsic chirality (i.e. a property arising from asymmetric achiral materials when observed from out of normal incidence directions), using photo-acoustic spectroscopy (PAS). PAS allows direct measurement of local absorption, by monitoring the heat produced and transferred to the surrounding air, regardless the transmitted, reflected, and scattered light that flows away from the sample. In conventional techniques, the CD is usually measured by taking into account only the extinction as transmitted (or reflected) light. In this study, we introduce a new PAS setup that employs an oblique-incidence laser to study extrinsic chirality in silver-coated self-assembled metasurfaces. Our experimental results reveal intriguing CD trends dependent on the angle of incidence and wavelength, indicative of extrinsic chirality. This study expands the application of PAS, enabling simultaneous analysis of multiple wavelengths and providing valuable insights into chiral metasurfaces.